The removal of silver nanoparticle by titanium tetrachloride and modified sodium alginate composite coagulants: floc properties, membrane fouling, and floc recycle

Abstract

In this study, a modified sodium alginate (MSA) composited with TiCl₄ was used to treat the synthetic Ag nanoparticles (AgNPs) water in coagulation-ultrafiltration process. The floc properties and membrane fouling of TiCl₄ and MSA composite coagulants (TiCl₄ + MSA) were investigated by a laser diffraction instrument and ultrafiltration fouling model. The recycle of the AgNP-containing flocs was evaluated by XRD and photocatalytic experiments. The results showed that TiCl₄ + MSA could achieve better coagulation performance than TiCl₄ alone with AgNP and DOC removal up to 97 and 59% at the optimum condition (pH = 5 and dosage = 12 mg TiCl₄/L). TiCl₄ + MSA produced larger and looser flocs than TiCl₄ and TiCl₄ + SA composite coagulant (TiCl₄ + SA), which was benefit for the inhibition of subsequence membrane fouling. The strongly attached external fouling resistance (R_ef-s) and the reversible internal fouling resistance (R_if-r) of TiCl₄ + MSA were only 43 and 39.2% of those achieved by TiCl₄ at the optimal coagulation condition. Besides, the adopted AgCl-TiO₂ could be recycled from AgNP-containing flocs. And MSA could promote the form of TiO₂ anatase. It gives us a possible way for silver nanoparticle recycle.