Insight into elemental mercury (Hg 0 ) removal from flue gas using UV/H 2 O 2 advanced oxidation processes

Abstract

Elemental mercury (Hg⁰) emitted from coal-fired power plants and municipal solid waste (MSW) incinerators has caused great harm to the environment and human beings. The strong oxidized ^•OH radicals produced by UV/H₂O₂ advanced oxidation processes were studied to investigate the performance of Hg⁰ removal from simulated flue gases. The results showed that when H₂O₂ concentration was 1.0 mol/L and the solution pH value was 4.1, the UV/H₂O₂ system had the highest Hg⁰ removal efficiency. The optimal reaction temperature was approximately 50 °C and Hg⁰ removal was inhibited when the temperature was higher or lower. The yield of ^•OH radicals during UV/H₂O₂ reaction was studied by electron paramagnetic resonance (EPR) analysis. UV radiation was the determining factor to remove Hg⁰ in UV/H₂O₂ system due to ^•OH generation during H₂O₂ decomposition. SO₂ had little influence on Hg⁰ removal whereas NO had an inhibitory effect on Hg⁰ removal. The detailed findings for Hg⁰ removal reactions over UV/H₂O₂ make it an attractive method for mercury control from flue gases.