A study of biochemical route on construction of waste battery ferrite applying for nickel removal

Abstract

Mn-Zn ferrite (Mn_1 − xZn_x Fe₂O₄, x = 0.2, 0.4, 0.6, and 0.8) nanomaterials were prepared by bioleaching and hydrothermal synthesis from waste Zn-Mn batteries. The materials were characterized by XRD, SEM, BET, VSM, CEC, and isoelectric point. It turned out when x = 0.4, synthesized Mn-Zn ferrite had best performance which was nanoferrite crystal structure with a specific surface area that reached 37.77 m²/g, the saturation magnetization was 62.85 emu/g, and isoelectric point and the CEC value were 7.33 and 43.51 mmol/100 g, respectively. In addition, the adsorption characteristics on Ni²⁺ were explored. The results of experiment suggested that data was more in line with the Freundlich model compared with Langmuir and Dubinin-Radushkevich isotherm models. Kinetics studies showed that pseudo-second-order kinetics was more suitable for describing the Ni²⁺ adsorption process where the maximum theoretical adsorption quantity was 52.99 mg/g. Thermodynamic parameters indicated the adsorption process can be spontaneous as an endothermic reaction, and warming was advantageous to adsorption. Besides, the adsorbent could be reused for six cycles with high removal efficiency. The magnetic and adsorptive properties of the adsorbent were promising, which had a high application value.

Graphical abstract

Fabrication process of nanometer ferrite by biological technology and hydrothermal synthesis for removal of Ni2+

Methylmercury and diphenyl diselenide interactions in Drosophila melanogaster: effects on development, behavior, and Hg levels

Abstract

Methylmercury (MeHg) is a highly toxic environmental pollutant which binds with a high affinity to selenol groups. In view of this, seleno-compounds have been investigated as MeHg antidotes. In the present study, we evaluated the effects of the co-exposure to MeHg and the seleno-compound diphenyl diselenide (PhSe)₂ on Drosophila melanogaster. We measured the survival rate, developmental survival, locomotor ability, reactive oxygen species (ROS) production, and Hg levels in D. melanogaster exposed to MeHg and/or (PhSe)₂ in the food. Exposure to MeHg caused a reduction in the survival rate, developmental survival, and locomotion in D. melanogaster. In addition, MeHg increased the ROS production and mercury levels in flies. The co-exposure to MeHg and (PhSe)₂ did not prevent the toxic effects of MeHg in D. melanogaster. On the contrary, the co-exposure enhanced the toxic effects on the locomotor ability and developmental survival. This effect may be explained by the fact that the co-exposure increased the Hg levels in body when compared to flies exposed only to MeHg, suggesting that MeHg and (PhSe)₂ interaction may increase Hg body burden in D. melanogaster which could contribute for the increased toxicity observed in the co-exposure.

Performance of Bi 2 O 3 /TiO 2 prepared by sol-gel on p-Cresol degradation under solar and visible light

Abstract

Photocatalytic degradation of p-Cresol was evaluated using the mixed oxide Bi₂O₃/TiO₂ (containing 2 and 20% wt. Bi₂O₃ referred as TB2 and TB20) and was compared with bare TiO₂ under simulated solar radiation. Materials were prepared by the classic sol-gel method. All solids exhibited the anatase phase by X-ray diffraction (XRD) and Raman spectroscopy. The synthesized materials presented lower crystallite size and Eg value, and also higher surface area as Bi₂O₃ amount was increased. Bi content was quantified showing near to 70% of theoretical values in TB2 and TB20. Bi₂O₃ incorporation also was demonstrated by X-ray photoelectron spectroscopy (XPS). Characterization of mixed oxides suggests a homogeneous distribution of Bi₂O₃ on TiO₂ surface. Photocatalytic tests were carried out using a catalyst loading of 1 g L⁻¹ under simulated solar light and visible light. The incorporation of Bi₂O₃ in TiO₂ improved the photocatalytic properties of the synthesized materials obtaining better results with TB20 than the unmodified TiO₂ under both radiation sources.