Iodine effective diffusion coefficients through volcanic rock: Influence of iodine speciation and rock geochemistry.

xlomafota13 shared this article with you from Inoreader Iodine effective diffusion coefficients through volcanic rock: Influence of iodine speciation and rock geochemistry. Via radioactive iodine Related Articles Iodine effective diffusion coefficients through volcanic rock: Influence of iodine speciation and rock geochemistry. J Contam Hydrol. 2020 Nov;235:103714 Authors: Neil CW, Telfeyan K, Sauer KB, Ware SD, Reimus P, Boukhalfa H, Roback R, Brug WP Abstract Accurate prediction of the subsurface transport of iodine species is important for the assessment of long-term nuclear waste repository performance, as well as monitoring compliance with the Comprehensive Nuclear-Test-Ban Treaty, given that radioiodine decays into radioxenon. However, the transport of iodine through intact geologic media is not well understood, compromising our ability to assess risk associated with radioiodine migration. The current study's goal is to quantify the matrix diffusion of iodine species through saturated volcanic rock, with particular attention paid to the redox environment and potential speciation changes. Diffusion experiments were run for iodide through lithophysae-rich lava, lithophysae-poor lava, and welded tuff, whereas iodate diffusion was studied through welded tuff. Iodine transport was compared with a conservative tracer, HDO, and effective diffusion coefficients were calculated. Likely due to a combination of size and anion exclusion e ffects, iodine species diffused more slowly than the conservative tracer through all rock types tested. Furthermore, oxidation of iodide to iodate was observed in the lithophysae-poor lava, affecting transport. Results provide much needed data for subsurface transport models that predict radioiodine migration from underground sources, and indicate the pressing need for geochemical and redox interactions to be incorporated into these models. PMID: 32987236 [PubMed - indexed for MEDLINE] View on the web Inoreader. Take back control of your news feed. Follow us on Twitter and Facebook.