Comparative performance of novel magnetic ion-imprinted adsorbents employed for Cd 2+ , Cu 2+ and Ni 2+ removal from aqueous solutions

Abstract

Novel magnetic ion-imprinted polymer was prepared by use of SBA-15 as functional monomer, ethylene glycol dimethacrylate as cross linker, diphenylcarbazide as ligand, and Cd²⁺, Cu²⁺, and Ni²⁺ as the template of ion source. The adsorption capacity of the synthesized adsorbent was 111, 95, and 87 mg g⁻¹, respectively for cadmium, copper, and nickel. The selectivity of the adsorbents examined in the presence of different cations including Na⁺, K⁺, Ca²⁺, Mg²⁺, Zn²⁺, Co²⁺, Fe²⁺, Mn²⁺, Hg²⁺, and Pb²⁺ indicated that the synthesized ion-imprinted adsorbents were highly selective for the appropriate cations. Kinetic studies indicated that the adsorption process was very fast and the equilibrium was established within 5 min and followed the pseudo-second-order kinetic model. The used ion-imprinted adsorbent was readily regenerated by elution with 2 M HNO₃, and the regenerated adsorbent retained most of its initial capacity. The calculated thermodynamic parameters indicated that the adsorption process was spontaneous and endothermic.