Fenton oxidation of municipal secondary effluent: comparison of Fe/Ce-RGO (reduced graphene oxide) and Fe 2+ as catalysts

Abstract

The advanced treatment of municipal secondary effluent by heterogeneous and homogeneous Fenton processes using Fe/Ce-RGO (reduced graphene oxide) and Fe²⁺ as catalysts was studied and compared. Sulfamethazine (SMT) was spiked in the effluent to examine the effectiveness of the emerging contaminant removal. The Fe/Ce-RGO catalyst was characterized using a scanning electron microscope (SEM) and cycle voltammetry curves. The removal of dissolved organic carbon (DOC), soluble chemical oxygen demand (SCOD), SMT, and ultraviolet-visible spectroscopy in 254 nm (UV₂₅₄) of municipal secondary effluents was examined. The DOC removal efficiency of secondary effluent (without addition of SMT) was 36.30% and 11.74% using Fe/Ce-RGO and Fe²⁺ as catalysts, respectively. The removal efficiency of DOC, SCOD, and SMT in heterogeneous Fenton process was higher than that in homogeneous Fenton process. The changes of three-dimensional excitation-emission matrix (3DEEM) fluorescence, soluble microbial products (SMPs), humic acids, and UV₂₅₄ were determined, and the results indicated that UV_254, aromatic proteins, and humic acids decreased rapidly in both processes; however, polysaccharides and protein-like substances were difficult to degrade. Although some toxic substances produced after Fenton-like treatment, the biodegradability of the treated effluent was enhanced.